Murai, Yuya et al. published their research in Polymer Journal (Tokyo, Japan) in 2013 | CAS: 200132-54-3

(1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3) belongs to quinuclidine derivatives. Quinuclidine acts as a catalyst, a chemical building block and is used in organic synthesis. It is employed to prepare quinine and alkaloids. Quinuclidine is an organic compound and a bicyclic amine and used as a catalyst and a chemical building block. It is a strong base with pKa of the conjugate acid of 19.5. It can be prepared by reduction of quinuclidone.Product Details of 200132-54-3

Polymeric pseudo-liquid membranes from poly(dodecyl methacrylate): KCl transport and optical resolution was written by Murai, Yuya;Yoshikawa, Masakazu. And the article was included in Polymer Journal (Tokyo, Japan) in 2013.Product Details of 200132-54-3 This article mentions the following:

A polymeric pseudo-liquid membrane (PPLM) was constructed from poly(dodecyl methacrylate) (PC12MA), which exhibited a rubbery state under membrane transport conditions and was used as the membrane matrix, and from dibenzo-18-crown-6 (DB18C6) or O-allyl-N-(9-anthracenylmethyl)cinchonidinium bromide (AAMC), which was used as a model transporter. Membrane performance was studied using KCl or a racemic mixture of phenylglycine (Phegly) as a model substrate. The PPLM with DB18C6 transported KCl. The membrane transport ability depended on the DB18C6 concentration, implying that DB18C6 worked as a transporter within the PC12MA membrane matrix. L-Phegly was preferentially transported over D-Phegly through the membrane with AAMC from the racemic mixture of Phegly, and the permselectivity was determined to be 1.55. The present results suggest that PPLMs are applicable not only in metal ion transport but also in optical resolution In the experiment, the researchers used many compounds, for example, (1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3Product Details of 200132-54-3).

(1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3) belongs to quinuclidine derivatives. Quinuclidine acts as a catalyst, a chemical building block and is used in organic synthesis. It is employed to prepare quinine and alkaloids. Quinuclidine is an organic compound and a bicyclic amine and used as a catalyst and a chemical building block. It is a strong base with pKa of the conjugate acid of 19.5. It can be prepared by reduction of quinuclidone.Product Details of 200132-54-3

Referemce:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider

 

Corey, E. J. et al. published their research in Organic Syntheses in 2003 | CAS: 200132-54-3

(1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3) belongs to quinuclidine derivatives. Quinuclidine exists in a number of naturally occurring compounds, biologically active agents, and privileged catalysts and ligands for asymmetric catalysis. Quinuclidine is an organic compound and a bicyclic amine and used as a catalyst and a chemical building block. It is a strong base with pKa of the conjugate acid of 19.5. It can be prepared by reduction of quinuclidone.Recommanded Product: (1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide

Preparation of O-allyl-N-(9-anthracenylmethyl)cinchonidinium bromide as a phase transfer catalyst for the enantioselective alkylation of glycine benzophenone imine tert-butyl ester: (4S)-2-(benzhydrylidenamino)pentanedioic acid, 1-tert-butyl ester-5-methyl ester was written by Corey, E. J.;Noe, Mark C.. And the article was included in Organic Syntheses in 2003.Recommanded Product: (1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide This article mentions the following:

The preparation of O-allyl-N-(9-anthracenylmethyl)cinchonidinium bromide (I·Br–), as a phase transfer catalyst for the enantioselective alkylation of glycine benzophenone imine tert-Bu ester, is reported. In the experiment, the researchers used many compounds, for example, (1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3Recommanded Product: (1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide).

(1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide (cas: 200132-54-3) belongs to quinuclidine derivatives. Quinuclidine exists in a number of naturally occurring compounds, biologically active agents, and privileged catalysts and ligands for asymmetric catalysis. Quinuclidine is an organic compound and a bicyclic amine and used as a catalyst and a chemical building block. It is a strong base with pKa of the conjugate acid of 19.5. It can be prepared by reduction of quinuclidone.Recommanded Product: (1S,2S,4S,5R)-2-((R)-(Allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide

Referemce:
Quinuclidine – Wikipedia,
Quinuclidine | C7H13N | ChemSpider

 

Zhang, He’s team published research in Journal of Chemical Research in 46 | CAS: 1160556-64-8

Journal of Chemical Research published new progress about 1160556-64-8. 1160556-64-8 belongs to quinuclidine, auxiliary class Mono-phosphine Ligands, name is 2′-(Dicyclohexylphosphino)-N2,N2,N6,N6-tetramethyl-[1,1′-biphenyl]-2,6-diamine, and the molecular formula is C19H22BNO5, Synthetic Route of 1160556-64-8.

Zhang, He published the artcileA new protocol for synthesizing diarylmethanes using a benzyltitanium reagent as a nucleophile, Synthetic Route of 1160556-64-8, the publication is Journal of Chemical Research (2022), 46(2), 17475198221091941, database is CAplus.

The first palladium-catalyzed cross-coupling of various substituted benzyltitaniums with aryl triflates is presented for the synthesis of diarylmethanes in yields of up to 94% through highly selective C-O bond functionalization. The benzyltitaniums act as nucleophiles to realize the C(sp2)-C(sp3) cross-coupling with high efficiency within short reaction times. The reactions proceed at 60°C and show excellent functional group tolerance.

Journal of Chemical Research published new progress about 1160556-64-8. 1160556-64-8 belongs to quinuclidine, auxiliary class Mono-phosphine Ligands, name is 2′-(Dicyclohexylphosphino)-N2,N2,N6,N6-tetramethyl-[1,1′-biphenyl]-2,6-diamine, and the molecular formula is C19H22BNO5, Synthetic Route of 1160556-64-8.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider

 

Truffault, Robert’s team published research in Compt. rend. in 207 | CAS: 20029-52-1

Compt. rend. published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C16H18Br2ClN3O3, Quality Control of 20029-52-1.

Truffault, Robert published the artcileCondensation of halogenated derivatives of benzene with unsaturated hydrocarbons and with halogenated derivatives of the latter under the influence of concentrated sulfuric acid as catalyst, Quality Control of 20029-52-1, the publication is Compt. rend. (1938), 676-8, database is CAplus.

Halogenated benzenes condense with olefins, in the presence of concentrated H2SO4, in the same way that benzene does (cf. C. A. 30, 4154.8), yielding p-substituted halogenated benzenes. Cyclohexene and PhCl react to form p-chlorocyclohexylbenzene (I), b16 134°, d20 1.070, nD20 1.5400; M. R. calculated 56.7, found 57.03. With PhBr the product is p-bromocyclohexylbenzene (II), b16 146°, d19 1.289, nD20 1.5605; M. R., calculated 59.58, found 60.0. Oxidation of I with CrO3 gave p-ClC6H4CO2H, m. 236°. The Mg derivative of II reacts with CO2 to form p-cyclohexylbenzoic acid, m. 200°. Allyl chloride (III) and PhCl react to form p-ClC6H4CHMeCHCl (IV), b16 117°, d21 1.185, nD20 1.538; M. R., calculated 49.9, found 49.9. With PhBr the product is p-BrC6H4CHMeCH2Cl (V), b15 134-5°, d21 1.416, nD21 1.558; M. R., calculated 52.8, found 53.2. The structures of IV and V were assigned on the basis of the structures established for the compounds prepared from C6H6 and III, loc. cit. Thus, H2SO4 may be used to prepare alkylbenzenes having halogenated side chains, which cannot be obtained in the Friedel-Crafts reaction.

Compt. rend. published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C16H18Br2ClN3O3, Quality Control of 20029-52-1.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider

 

Sridhar, Arun Srikanth’s team published research in Soft Matter in 18 | CAS: 1761-71-3

Soft Matter published new progress about 1761-71-3. 1761-71-3 belongs to quinuclidine, auxiliary class Ploymers, name is 4,4-Diaminodicyclohexyl methane, and the molecular formula is C2H2N4O2, Category: quinuclidine.

Sridhar, Arun Srikanth published the artcileEffect of stoichiometry on crosslinked epoxy resin characteristics: structural heterogeneities, topological defects, properties, free volume and segmental mobility, Category: quinuclidine, the publication is Soft Matter (2022), 18(12), 2354-2372, database is CAplus and MEDLINE.

Exptl. studies have shown that changes in stoichiometry (R, ratio of amine groups to epoxy groups) cause considerable variations in the properties of epoxy-amine systems. Rationales based on free volume concepts have been routinely used to address these variations in properties but have hardly been satisfactorily substantiated. Many of these rationales remain as unverified conjectures to date. Substantiating these rationales will certainly bolster our understanding of the structure-stoichiometry-property relationship, but is difficult, due to inherent challenges involved in unambiguously characterizing the structural heterogeneities induced by changes in stoichiometry (structural heterogeneities include compositional distribution in the functionality of monomers, non-uniform dispersion of elastic chains and topol. defects). The aim of the present work is to gain mol.-level insights into this relationship and to verify the rationales that rely on free volume concepts used for addressing the variations in properties with stoichiometry, with the help of all-atom mol. dynamics (MD) simulations. Five epoxy-amine systems with varying R ranging from 0.4 to 3, including the stoichiometric system (R = 1), were considered for these purposes. The properties of interest namely d., glass transition temperature (Tg) and thermal expansion coefficient in the rubbery state (αrl) of these systems were predicted. The local structure, fractional free volume and segmental mobility of these systems were then subsequently characterized as a function of stoichiometry and the results were analyzed in detail. The role played by defects in properties and fractional free volume was then investigated. The results revealed significant insights into the compositional distribution of monomers with different functionalities as well as offered insights into the dispersion state and mobility of dangling chains, sols and elastic chains in the systems. Further, strong correlations were found between defect composition, fractional free volume at an elevated temperature (600 K) and thermomech. properties (Tg and αrl) and it was established that the key mechanism underlying these correlations was the plasticization caused by defects. Anal. based on the rule of mixture models showed that these correlations were found to be in good agreement with the interpretations based on free volume concepts. The results also revealed a strong neg. correlation between fractional free volume at room temperature and defect composition, a phenomenon typically associated with the antiplasticization effect.

Soft Matter published new progress about 1761-71-3. 1761-71-3 belongs to quinuclidine, auxiliary class Ploymers, name is 4,4-Diaminodicyclohexyl methane, and the molecular formula is C2H2N4O2, Category: quinuclidine.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider

 

Neunhoeffer, Otto’s team published research in Justus Liebigs Annalen der Chemie in 526 | CAS: 20029-52-1

Justus Liebigs Annalen der Chemie published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, SDS of cas: 20029-52-1.

Neunhoeffer, Otto published the artcileTricyclohexylmethane series. III, SDS of cas: 20029-52-1, the publication is Justus Liebigs Annalen der Chemie (1936), 58-65, database is CAplus.

p-Cyclohexylphenylmagnesium iodide and 13 g. Me p-cyclohexylbenzoate give 3 g. p,p’-dicyclohexylbiphenyl (I), m. 205°; some p,p’-dicyclohexylbenzophenone, m. 135°; and as the principal fraction, tri-(p-cyclohexylphenyl)carbinol (II), m. 168°. The action of CO2 upon the Grignard reagent gives p-cyclohexylbenzoic acid, I and II. II in concentrated H2SO4 gives an intensive red-yellow color; II does not react with the usual reagents to form a halogen derivative or a Me ether. The action of Ag upon tricyclohexylmethyl bromide is complete in about 3 months; the action of K-Na gives dicyclohexylcyclohexylidenemethane, m. 52°. The cyclohexyl residue does not favor the formation of free radicals.

Justus Liebigs Annalen der Chemie published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, SDS of cas: 20029-52-1.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider

 

Neunhoeffer, Otto’s team published research in Journal fuer Praktische Chemie (Leipzig) in 133 | CAS: 20029-52-1

Journal fuer Praktische Chemie (Leipzig) published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, Safety of 4-Cyclohexylbenzoic acid.

Neunhoeffer, Otto published the artcileSynthesis and nitration of phenylcyclohexane, Safety of 4-Cyclohexylbenzoic acid, the publication is Journal fuer Praktische Chemie (Leipzig) (1932), 95-109, database is CAplus.

In the preparation of phenyleyelohexane (I) the yield is increased with an excess of C6H6; thus, 1 mol. cyclohexyl chloride and 3 mols. C6H6 give 0.55 mol. I and 0.18 mol. dicyclohexylbenzene (II), while 12 mols. C6H6 gives 0.8 mol. I and 0.08 mol. II. Degradation of I with O3 gives cyclopentylacetic acid, characterized as the amide, m. 149°. Oxidation of II gives terephthalic acid. Nitration of I in Ac2O with fuming HNO3 gives a mixture of p- (III) and o-nitrocyclohexylbenzenes (IV), in the ratio 78: 22; III b0.6 142°, m. 57°; IV b0.5 113°, m. 45°. Electrolytic reduction of III gives quantitatively p-cyelohexylaniline; through the diazo reaction this gives 90% of pcyclohexyliodobenzene, b0.5 117°, m. 4°, and 42% of nitrile, b0.5 123°, m. 41°; hydrolysis gives p-cyclohexylbenzoic acid, m. 196°. Electrolytic reduction of IV gives o-cyclohexylaniline,b0.6 106°.m.13°; Acderiv.,m.101°; Bzderiv.,m.154°. III is trimorphic, m. 54°, 56° and 57°.

Journal fuer Praktische Chemie (Leipzig) published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, Safety of 4-Cyclohexylbenzoic acid.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider

 

Burgess, Laurence E.’s team published research in Synthetic Communications in 27 | CAS: 20029-52-1

Synthetic Communications published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, Product Details of C13H16O2.

Burgess, Laurence E. published the artcileThe preparation of immunosuppressant SR-31747, Product Details of C13H16O2, the publication is Synthetic Communications (1997), 27(12), 2181-2191, database is CAplus.

The preparation of immunosuppressant SR-31747 was described. Attempts to install a (Z)-allyl amine included Lindlar partial hydrogenation and vinyl stannane methodologies. Ultimately, the Wittig olefination of 3-chloro-4-cyclohexylbenzaldehyde with the ylide derived from β-aminoethyl phosphonium salt [i.e., [2-(cyclohexylethylamino)ethyl]triphenylphosphonium bromide] proved successful.

Synthetic Communications published new progress about 20029-52-1. 20029-52-1 belongs to quinuclidine, auxiliary class Carboxylic acid,Benzene, name is 4-Cyclohexylbenzoic acid, and the molecular formula is C13H16O2, Product Details of C13H16O2.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider

 

Liu, Xin’s team published research in Chemical Communications (Cambridge, United Kingdom) in 58 | CAS: 1761-71-3

Chemical Communications (Cambridge, United Kingdom) published new progress about 1761-71-3. 1761-71-3 belongs to quinuclidine, auxiliary class Ploymers, name is 4,4-Diaminodicyclohexyl methane, and the molecular formula is C13H26N2, Recommanded Product: 4,4-Diaminodicyclohexyl methane.

Liu, Xin published the artcileHydrogenative depolymerization of silicon-modified polyureas, Recommanded Product: 4,4-Diaminodicyclohexyl methane, the publication is Chemical Communications (Cambridge, United Kingdom) (2022), 58(35), 5415-5418, database is CAplus and MEDLINE.

Silicon-modified polyureas were depolymerized by hydrogenation in the presence of Ru and Mn catalysts. Yields of up to 84% of the aliphatic diamine and 81% of silicon-containing diamine were achieved with a com. available PNP-Ru catalyst.

Chemical Communications (Cambridge, United Kingdom) published new progress about 1761-71-3. 1761-71-3 belongs to quinuclidine, auxiliary class Ploymers, name is 4,4-Diaminodicyclohexyl methane, and the molecular formula is C13H26N2, Recommanded Product: 4,4-Diaminodicyclohexyl methane.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider

 

Huang, Yao’s team published research in Chemical Science in 13 | CAS: 1160556-64-8

Chemical Science published new progress about 1160556-64-8. 1160556-64-8 belongs to quinuclidine, auxiliary class Mono-phosphine Ligands, name is 2′-(Dicyclohexylphosphino)-N2,N2,N6,N6-tetramethyl-[1,1′-biphenyl]-2,6-diamine, and the molecular formula is C28H41N2P, Category: quinuclidine.

Huang, Yao published the artcileHighly regioselective and diastereodivergent aminomethylative annulation of dienyl alcohols enabled by a hydrogen-bonding assisting effect, Category: quinuclidine, the publication is Chemical Science (2022), 13(8), 2317-2323, database is CAplus and MEDLINE.

A ligand-controlled palladium-catalyzed highly regioselective and diastereodivergent aminomethylative annulation of dienyl alcs. with aminals were established, which allowed for producing either cis- or trans-disubstituted isochromans in good yields with complete regioselectivity and good to excellent diastereoselectivity. Moreover, the chiral cis-products were also obtained in good yields with up to 94% ee by using a chiral phosphinamide as the ligand. Mechanistic studies revealed that the hydroxyl group played a key role in facilitating the Pd-catalyzed Heck insertion regioselectively taking place across the internal C=C bond of conjugated dienes.

Chemical Science published new progress about 1160556-64-8. 1160556-64-8 belongs to quinuclidine, auxiliary class Mono-phosphine Ligands, name is 2′-(Dicyclohexylphosphino)-N2,N2,N6,N6-tetramethyl-[1,1′-biphenyl]-2,6-diamine, and the molecular formula is C28H41N2P, Category: quinuclidine.

Referemce:
https://en.wikipedia.org/wiki/Quinuclidine,
Quinuclidine | C7H13N | ChemSpider